Water-Soluble Neutral Calix[4]arene-Lanthanide Complexes: Synthesis and Luminescence Properties.

نویسندگان

  • Frank J. Steemers
  • Hans G. Meuris
  • Willem Verboom
  • David N. Reinhoudt
  • Erik B. van Der Tol
  • Jan W. Verhoeven
چکیده

Water-soluble calix[4]arenes 10a,b with chromophores ("antenna") attached to the lower rim via a short spacer are described. In the neutral lanthanide complexes of 10a,b photoexcitation of the antenna induces lanthanide emission via intramolecular energy transfer. Calix[4]arene 10b with a chrysene moiety as sensitizer shows strong lanthanide emission for Eu(3+) with an excitation maximum at lambda = 363 nm.

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عنوان ژورنال:
  • The Journal of organic chemistry

دوره 62 13  شماره 

صفحات  -

تاریخ انتشار 1997